Wednesday, March 24, 2010

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's law Gay-Lussac

Gay Lussac was a French-born scientist, who discovered that when two gases react, the relationship between the volumes of reagents and products are always the same as the relationship between whole numbers.

For example, a volume of hydrogen reacts with chlorine giving a volume of two volumes of hydrochloric acid, according to the reaction:

H + Cl → HCl

Again, two volumes of hydrogen react with oxygen to give a volume of two volumes of water, according to the reaction:

H + O2 → H2O


First Law of Gay Lussac : constant pressure, the volume of a gas increases with ' increasing temperature.

V(T)={V}_0 \cdot (1 + \alpha T)\,\!

V0 = volume of gas at a temperature of zero degrees Celsius
V (T) = volume to a temperature greater than zero:
Alpha = expansion coefficient of gas (volume increase immediately by a unit volume gas when its temperature rises 1 ° C).

If the temperature is not taken as a reference in degrees centigrade but in degrees Kelvin, the law becomes:

V(T)={V}_o \cdot {\alpha}\cdot T\,\!


second law Gay Lussac : constant volume the pressure of a gas increases with temperature.

 p(T)={p}_o \cdot (1+{\alpha}\cdot T)\,\!

P0 = pressure of a gas at 0 ° C;
P (T) = pressure at a temperature greater than 0 ° C;
Alpha coefficient of expansion of the gas (relative increase of gas pressure when the temperature rises 1 ° C).

If the temperature is in degrees Kelvin, the law becomes:

p(T)={p}_o \cdot {\alpha}\cdot T\,\!



Both these laws are valid not too high pressures and temperatures close to the liquefaction of gases. It is therefore more occurred when a gas behaves like a perfect (ideal).

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